Rh(III)-catalyzed oxidative coupling of N-aryl-2-aminopyridine with alkynes and alkenes |
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| Authors: | Chen Jinlei Song Guoyong Pan Cheng-Ling Li Xingwei |
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| Institution: | State Key Laboratory of Theoretical and Computational Chemistry, Jilin University, Changchun 130023, P. R. China. |
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| Abstract: | RhCp*Cl(2)](2) (1-2 mol %) can catalyze the oxidative coupling of N-aryl-2-aminopyridines with alkynes and arylates to give N-(2-pyridyl)indoles and N-(2-pyridyl)quinolones, respectively, using Cu(OAc)(2) as an oxidant. Coupling with styrenes gave mono- and/or disubstituted olefination products. |
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