Oxidative desulfurization of model diesel oil over Ti-containing molecular sieves using hydrogen peroxide |
| |
| Authors: | Suhua Cui Feng Ma Yaquan Wang |
| |
| Affiliation: | (1) Key Laboratory for Green Chemical Technology, School of Chemical Engineering and Technology, Tianjin University, Tianjin, 300072, P. R. of China |
| |
| Abstract: | Three Ti-containing molecular sieves were studied in the oxidative desulfurization (ODS) of model diesel oil with hydrogen peroxide. Under optimal conditions, dibenzothiophene (DBT) conversion up to 80.6% and 42.6% could be obtained with Ti-HMS and Ti-MSU as catalysts, respectively. However, there is no activity in the sulfoxidation of DBT over TS-1. Effects of the TiO2/SiO2 ratio in Ti-HMS and reaction conditions, such as the reaction temperature, reaction time, n(H2O2)/n(S) on the sulfur removal were investigated. |
| |
| Keywords: | Ti-HMS dibenzothiophene hydrogen peroxide oxidative desulfurization |
| 本文献已被 SpringerLink 等数据库收录！ |
|
