Accounting for the Adsorption of Anions When Interpreting the Mechanism of Electrodeposition of Metals from Complex Electrolytes: The Reaction Order by the Electrochemically Active Ion |
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Authors: | Email author" target="_blank">N?A?RogozhnikovEmail author |
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Institution: | (1) Institute of Solid-State Chemistry and Mechanochemistry, Siberian Division, Russian Academy of Sciences, ul. Michurina 15, Novosibirsk, 630091, Russia |
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Abstract: | The relationship between the current and the bulk concentration of complex ions during concurrent specific adsorption of an electrochemically active complex ion and a complexing ligand is considered. The effect of parameters that characterize adsorption of such ions and the structure of the electrical double layer on this relationship is analyzed.__________Translated from Elektrokhimiya, Vol. 41, No. 7, 2005, pp. 817–822.Original Russian Text Copyright © 2005 by Rogozhnikov. |
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Keywords: | electrical double layer adsorption electrodeposition |
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