| 金属促进的1H-磷杂环戊二烯的合成方法学研究 |
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| 引用本文： | 张文雄,郑卫新,孔凡志,席振峰. 金属促进的1H-磷杂环戊二烯的合成方法学研究[J]. 有机化学, 2004, 24(11): 1323-1331 |
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| 作者姓名： | 张文雄 郑卫新 孔凡志 席振峰 |
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| 作者单位： | 北京大学化学与分子工程学院,北京,100871 |
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| 摘 要： | 1H-磷杂环戊二烯的合成、反应和性质的研究已成为有机合成化学和金属有机化学的主要研究热点之一并得到了迅猛的发展,它们在光电材料、配位化学和选择性催化等方面有重要的应用价值.从金属有机化学的角度,系统地总结了近十年来1H-磷杂环戊二烯的合成化学新反应、新方法及应用.
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| 关 键 词： | 金属有机化合物 1H-磷杂环戊二烯 合成 |
| 修稿时间： | 2003-10-27 |
Novel Synthetic Methodologies of 1H-Phospholes Mediated by Organometallic Compounds |
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| ZHANG,Wen-Xiong ZHENG,Wei-Xin KONG,Fan-Zhi XI,Zhen-Feng. Novel Synthetic Methodologies of 1H-Phospholes Mediated by Organometallic Compounds[J]. Chinese Journal of Organic Chemistry, 2004, 24(11): 1323-1331 |
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| Authors: | ZHANG Wen-Xiong ZHENG Wei-Xin KONG Fan-Zhi XI Zhen-Feng |
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| Abstract: | Currently, the syntheses, reactions and properties of 1H-phospholes have become an area of great interest in organic synthesis and organometallic chemistry, because they may have potential uses in opt-electronic materials, coordination chemistry and selective catalysis. This review describes recent development on metal-mediated novel synthetic methodologies of 1H-phospholes and their utilities. |
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| Keywords: | organometallic compound 1H-phosphole synthesis |
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