One step assembly of a nonanuclear CrIII2NiII7 bimetallic cyanide bridged complex |
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| Authors: | Rebilly Jean-Noël Catala Laure Rivière Eric Guillot Régis Wernsdorfer Wolfgang Mallah Talal |
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| Affiliation: | Laboratoire de Chimie Inorganique, ICMMO, CNRS UMR 8613, Université Paris-Sud, Bat 420, F-91405, Orsay, France. |
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| Abstract: | ![]()
The reaction of hexacyanochromate with connectivity 6 and a mononuclear Ni complex bearing a bulky tridentate macrocycle leads in one step to the formation of a nonanuclear Cr2Ni7 complex with central low spin and peripheral high spin Ni ions; fast tunnelling of the magnetization is observed at low temperature by micro-SQUID studies on a single crystal. |
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