Asymmetric induction by helical poly(amino acid)s in cyanosilylation of aldehydes |
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| Authors: | Kengo Akagawa Kazuaki Kudo |
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| Affiliation: | Institute of Industrial Science, University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153-8505, Japan |
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| Abstract: | It was first demonstrated that helical poly(amino acid)s have an ability to induce enantioselectivity in the cyanosilylation of aldehydes. The helicity of poly(amino acid)s and the N-terminal amino group were essential for the enantioinduction of the reaction. |
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| Keywords: | Cyanosilylation Poly(amino acid)s Polyleucine α-Helix Asymmetric induction |
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