A novel reaction cascade leading to a spontaneous intramolecular dipolar cycloaddition through simultaneous generation of 1,3-dipole and dipolarophile |
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| Authors: | Nagabushanam Kalyanam Keshav R Rapole Ramanujam Rajendran Muhammed Majeed |
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| Institution: | 1. Sabinsa Corporation, 20 Lake Drive, East Windsor, NJ 08520, United States;2. Sami Labs Limited, Peenya Industrial Area, Bangalore 560058, India |
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| Abstract: | Ornithine methyl ester reacts with aromatic aldehydes to generate bis-Schiff bases, which depending on the structure of the aromatic aldehyde, further undergo an intramolecular cycloaddition through the transient formation of a reactive 1,3-dipole. |
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| Keywords: | Azomethine ylid 1 3-Dipolar addition Cycloaddition Dipolarophile Stereoselective Bis-Schiff bases of ornithine |
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