Diffraction of electrons in the CubicTi5O5 superstructure of titanium monoxide

Annealed titanium monoxide TiO_1.087 has been studied by the electron diffraction method. A cubic model of the Ti₅O₅ superstructure (Ti₅O₅ (Ti₉₀?₁₈O₉₀??₁₈)) of nonstoichiometric titanium monoxide Ti _x O _z has been proposed on the basis of experimental data and representations about the disorder-order transition channel. It has been shown that reflections observed on the electron diffraction pattern are identified in the space group $Pm\bar 3m$ . The period of the unit cell of the cubic Ti₅O₅ superstructure is larger than that for the B1 basic disordered structure of Ti _x O _z monoxide by a factor of 3. The disorder-order transition channel Ti _x O _z (space group $Fm\bar 3m$ )-Ti₅O₅ (space group $Pm\bar 3m$ ) includes 75 superstructure vectors of seven stars {k ₁₀}, {k ₇}, {k ₆₍₁₎}, {k ₆₍₂₎}, {k ₄₍₁₎}, {k ₄₍₂₎}, and {k ₁}. The distribution functions of Ti and O atoms over the sites of the cubic Ti₅O₅ (space group $Pm\bar 3m$ ) superstructure have been calculated.