Synthesis of polycyclic molecules by double C(sp2)-H/C(sp3)-H arylations with a single palladium catalyst |
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| Authors: | Pierre Cathleen Baudoin Olivier |
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| Institution: | Universite? Claude Bernard Lyon 1, CNRS UMR 5246-Institut de Chimie et Biochimie Mole?culaires et Supramole?culaires, CPE Lyon, 43 Boulevard du 11 Novembre 1918, 69622 Villeurbanne, France. |
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| Abstract: | Polycyclic molecules were obtained in good yields by double C(sp(2))-H/C(sp(3))-H arylations mediated by a single palladium/phosphine catalyst. Both double intermolecular/intramolecular and intramolecular/intramolecular C-C couplings were performed successfully, which indicates that this concept has a broad applicability for the rapid construction of molecular complexity. |
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