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Synthesis and Adsorption Properties of Polystyrene-supported Chelating Resins Containing Heterocyclic Functional Groups
引用本文:Chun Nuan JI Rong Jun QU Chun Hua WANG Chang Mei SUN Qing Hua TANG. Synthesis and Adsorption Properties of Polystyrene-supported Chelating Resins Containing Heterocyclic Functional Groups[J]. 中国化学快报, 2005, 16(9): 1193-1196
作者姓名:Chun Nuan JI Rong Jun QU Chun Hua WANG Chang Mei SUN Qing Hua TANG
作者单位:[1]School of Chemistry and Materials Science Yantai Normal University, Yantai 264025 [2]School of Materials Science and Engineering, Tianjin University, Tianjin 300072
基金项目:Postdoctoral Science Foundation of China,山东省自然科学基金,国家自然科学基金
摘    要:
A series of new chelating resins with incorporating heterocyclic functional groups: pyridine, thiadizole, benzothizole into macroporous chloromethylated polystyrene were synthesized via hydrophilic spacer arm of polyethylene glycol containing sulfur. These chelating resins were found to show high adsorption capacities for Ag^+, Hg^2+, Au^3+ and Pd^2+, and the presence of spacer arm can enhance adsorption ability due to increase the hydrophilicity of the chelating resins.

关 键 词:杂环化合物 聚苯乙烯 树脂 螯合效应 合成方法 吸附功能
收稿时间:2004-11-15

Synthesis and Adsorption Properties of Polystyrene-supported Chelating Resins Containing Heterocyclic Functional Groups
Chun Nuan JI,Rong Jun QU,Chun Hua WANG,Chang Mei SUN,Qing Hua TANG. Synthesis and Adsorption Properties of Polystyrene-supported Chelating Resins Containing Heterocyclic Functional Groups[J]. Chinese Chemical Letters, 2005, 16(9): 1193-1196
Authors:Chun Nuan JI  Rong Jun QU  Chun Hua WANG  Chang Mei SUN  Qing Hua TANG
Abstract:
A series of new chelating resins with incorporating heterocyclic functional groups:pyridine, thiadizole, benzothizole into macroporous chloromethylated polystyrene were synthesized via hydrophilic spacer arm of polyethylene glycol co ntaining sulfur. These chelating resins were found to show high adsorption capacities for Ag , Hg2 , Au3 and Pd2 , and the presence of spacer arm can enhance adsorption ability due to increase the hydrophilicity of the chelating resins.
Keywords:Chelating resins  heterocyclic functional groups  spacer arm  adsorption  metal ions
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