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Structure of Co-Doped Alq3 thin films investigated by grazing incidence X-ray absorption fine structure and Fourier transform infrared spectroscopy
Authors:Lin Liang  Pang Zhiyong  Fang Shaojie  Wang Fenggong  Song Shumei  Huang Yuying  Wei Xiangjun  Yu Haisheng  Han Shenghao
Affiliation:School of Physics, State Key Laboratory of Crystal Materials, Shandong University, Jinan, P R China.
Abstract:The structural properties of Co-doped tris(8-hydroxyquinoline)aluminum (Alq(3)) have been studied by grazing incidence X-ray absorption fine structure (GIXAFS) and Fourier transform infrared spectroscopy (FTIR). GIXAFS analysis suggests that there are multivalent Co-Alq(3) complexes and the doped Co atoms tend to locate at the attraction center with respect to N and O atoms and bond with them. The FTIR spectra indicate that the Co atoms interact with the meridional (mer) isomer of Alq(3) rather than forming inorganic compounds.
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