A highly efficient general synthesis of phosphine-borane complexes |
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| Authors: | James McNulty Yuehui Zhou |
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| Institution: | a Department of Chemistry, McMaster University, 1280 Main Street West, Hamilton, Ontario, Canada L8S 4M1
b Cytec Canada Inc., PO Box 240, Niagara Falls, Ontario, Canada L2E 6T4 |
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| Abstract: | A general synthesis of phosphine-borane complexes proceeding in high yield in a safe, green process from borane generated in situ from sodium borohydride is described. The procedure also allows simultaneous carbonyl reduction and phosphine-borane formation on air-sensitive bulky phosphine derivatives. |
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| Keywords: | phosphine phosphine borane |
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