Effect of lithium chloride on allylation of zirconacyclopentadienes |
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Authors: | Lian Leng Chao Chen Chunbo Lai |
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Institution: | Key Laboratory for Bioorganic Phosphorus Chemistry of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, China |
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Abstract: | The effects of lithium chloride on the allylation of zirconacyclopentadienes with allylic halides in the presence of CuCl have been studied. It is found that mono-allylation products are formed predominantly in the absence of lithium chloride, while the presence of lithium chloride leads to the formation of di-allylation products. |
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