Synthesis of heliannuol D, an allelochemical from Helianthus annus |
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| Authors: | Subir K. Sabui |
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| Affiliation: | Department of Organic Chemistry, Indian Association for the Cultivation of Science, Jadavpur, Kolkata 700-032, India |
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| Abstract: | ![]()
A synthesis of heliannuol D 1 is described involving regioselective oxidation of the benzoxabicyclo[3.2.1]octanone 20 followed by hydrogenolysis to generate the benzoxepane ring system of 1. |
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| Keywords: | Allelochemical Heliannuol D Benzobicyclo[3.2.1]octanone oxidative cleavage Benzoxepane ring system |
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