Resonant light-scattering spectra of molecules with double-well vibrational potentials |
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Authors: | V A Morozov Yu M Dubina |
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Institution: | 1.N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences,Moscow,Russia;2.V. A. Trapeznikov Institute of Control Sciences, Russian Academy of Sciences,Moscow,Russia |
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Abstract: | Examples of excitation spectra lines for resonant Rayleigh and Raman scattering by model molecules with a double-well potential
in a vibrational subsystem in both the ground and excited states are calculated based on numerical solutions of a stationary
Schrodinger equation for a particle in a double-well potential. The obtained results demonstrate that the given formalism
can be used, e.g., to establish the mechanism for transferring the proton of an intramolecular H-bond in the excited molecular
electronic state upon monochromatic irradiation using resonant light-scattering spectroscopic data. |
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