A canted antiferromagnetic ordered phase of cyanido-bridged Mn(III)(2)Re(IV) single-chain magnets |
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| Authors: | Indrani Bhowmick Elizabeth A Hillard Pierre Dechambenoit Claude Coulon T David Harris Rodolphe Clérac |
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| Affiliation: | CNRS, CRPP, UPR 8641, F-33600 Pessac, France. clerac@crpp-bordeaux.cnrs.fr. |
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| Abstract: | A new cyanido-bridged Re(IV)-Mn(III) heterometallic 1D system, [Mn(III)(5-Me-saltmen)](2)[Re(IV)Cl(4)(CN)(2)]·3CH(3)CN (), was designed and structurally characterized. Interchain interactions stabilize a canted antiferromagnetic ordered state below 6.2 K that does not prevent slow relaxation of the magnetization reminiscent of the single-chain magnet properties of the individual chains. |
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