| Promoting effect of ethanol on the synthesis of N-（2-methylphenyl）-hydroxylamine from o-nitrotoluene in Zn/H2O/CO2 system |
| |
| 作者姓名： | Shi Juan Liu Yan Hua Wang Yuan Ping Hao Jing Yang Jiang |
| |
| 作者单位： | a College of Chemical Engineering, State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012, China;b College of Chemistry, Jilin Normal University, Siping 136000, China |
| |
| 基金项目： | supported by the Doctoral Fund of Ministry of Education of China(No.20070141046); the Fund of Education Department of Liaoning Province(No.[2006]124) |
| |
| 摘 要： | The promoting effect of ethanol on the synthesis of N-（2-methylphenyl）hydroxylamine from o-nitrotoluene in Zn/H2O/CO2 system was observed.By adding appropriate amount of ethanol,the selectivity of N-（2-methylphenyl）hydroxylamine increased from 71%to 90%when the reduction was carried out at 25℃under normal pressure of CO2.
|
| 关 键 词： | o-Nitrotoluene N-(2-Methylphenyl)hydroxylamine Reduction Zn CO2/H2O |
| 本文献已被 CNKI 等数据库收录！ |
| 点击此处可从《中国化学快报》浏览原始摘要信息 |
|
点击此处可从《中国化学快报》下载免费的PDF全文 |
