Synthesis and metal complexation studies of [2n]thiacalix[m]arene[m]pyrazine |
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| Authors: | Mahendra P Sonawane Stijn Boodts Joice Thomas |
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| Institution: | Molecular Design and Synthesis, Department of Chemistry, KU Leuven, Celestijnenlaan 200F, 3001 Leuven, Belgium |
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| Abstract: | Novel 2n]thiacalixarenepyrazine and 2n]thiacalixarenetriazine systems were synthesised by one-pot SNAr reactions. A screening of the metal-complexing ability of 26]hexathiacalix3]arene3]pyrazine revealed its affinity for CuI, CuII and AgI metal salts. |
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| Keywords: | SNAr reactions [2n]Calixarenes metal binding pyrazine triazine |
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