Preparation of block copolymer by atom transfer radical seeded emulsion polymerization |
| |
| Authors: | Masayoshi?Okubo mailto:okubo@cx.kobe-u.ac.jp" title=" okubo@cx.kobe-u.ac.jp" itemprop=" email" data-track=" click" data-track-action=" Email author" data-track-label=" " >Email author,Hideto?Minami,Jian?Zhou |
| |
| Affiliation: | (1) Graduate School of Science and Technology, Kobe University, 657–8501 Kobe, Japan;(2) Department of Chemical Science and Engineering, Faculty of Engineering, Kobe University, 657–8501 Kobe, Japan |
| |
| Abstract: | ![]()
Poly(i-butyl methacrylate)-polystyrene block copolymer was successfully prepared in an aqueous medium by two-step atom transfer radical polymerization (ATRP), mini-emulsion- and seeded-ATRP, in which ethyl 2-bromoisobutyrate/CuBr/4,4 -dinonyl-2,2-dipyridyl initiator system was used. The block copolymer had narrow molecular weight distribution (Mw/Mn=1.1) and the number-average molecular weight measured by gel permeation chromatography agreed with the calculated value.Part CCXLVIII of the series  Studies on Suspension and Emulsion |
| |
| Keywords: | Atom transfer radical polymerization (ATRP) Mini-emulsion polymerization Seeded polymerization Living radical polymerization Block polymer |
| 本文献已被 SpringerLink 等数据库收录！ |
|
