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Complexation of Ni (II) and Zn(II) ions by 3-(1-naphthyI)-2-mercaptopropenoic acid
Authors:Alvaro Izquierdo  José L. Beltrán
Affiliation:(1) Department of Analytical Chemistry, University of Barcelona, Diagonal 647, E-08028 Barcelona, Spain
Abstract:
The complexation equilibria between Ni(II) and Zn(II) metal ions with 3-(1-naphthyl)-2-mercaptopropenoic acid (H2NMP) were studied by glass electrode potentiometry, at 25 °C and 1.0 mol·dm–3 in NaClO4 as constant ionic medium in 50% (v/v) water-ethanol solutions. Formation constants for the complexes Ni(NMP), Ni(NMP)22–, Zn(NMP) and Zn(NMP)22–, refined by the MINIGLASS program, are reported.
Keywords:3-naphthyl-1–  2-mercaptopropenoic acid  complexation constants  potentiometry  MINIGLASS program
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