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Hydro­gen‐bonding patterns in 2‐amino‐4,6‐di­methyl­pyrimidinium hydrogen sulfate
Authors:Madhukar Hemamalini  Packianathan Thomas Mu­thiah  Urszula Rychlewska  Agnieszka Plutecka
Abstract:In the title compound, C6H10N3+·HSO4, the asymmetric unit consists of a hydrogen sulfate anion and a 2‐amino‐4,6‐di­methyl­pyrimidinium cation. The hydrogen sulfate anions self‐assemble through O—H⋯O hydrogen bonds, forming supramolecular chains along the b axis, while the organic cations form base pairs via N—H⋯N hydrogen bonds. The amino­pyrimidinium cations join to the sulfate anions via a pair of hydrogen bonds donated from the pyrimidinium protonation site and from the exo amine group cis to the protonated site.
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