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Dimeric hexakis(4‐methyl­benzoato)­bis(1,10‐phenanthroline)didyspros­ium(III)
Authors:Xia Li  Zhuo‐Yong Zhang  Dao‐Yong Wang  Hai‐Bin Song  Ying‐Quan Zou
Abstract:The title compound, Dy2(C8H7O2)6(C12H8N2)2], forms binuclear complexes, viz. di‐μ‐4‐methyl­benzoato‐κ4O:O′‐bisbis(4‐methyl­benzoato‐κ2O,O′)(1,10‐phenanthroline‐κ2N,N′)dyspros­ium(III)] tetra‐μ‐4‐methyl­benzoato‐κ8O:O′‐bis(4‐methyl­benzoato‐κ2O,O′)(1,10‐phenanthroline‐κ2N,N′)dyspros­ium(III)]. There are two independent binuclear com­plexes in the asymmetric unit, both of which are centrosymmetric. In one, the DyIII ions are linked by two bridging 4‐­methyl­benzoate groups, while in the other, the DyIII ions are linked by four bridging 4‐methyl­benzoate groups. The remaining 4‐methyl­benzoate groups and 1,10‐phenanthroline units coordinate to just one metal ion in bidentate modes.
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