Hemilability and nonrigidity in metal complexes of bidentate P,PS donor ligands |
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| Authors: | J.W. Faller Suzanna C. Milheiro Jonathan Parr |
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| Affiliation: | 1. Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC 29208, USA;2. Department of Chemistry, Texas A&M University, College Station, TX 77843, USA;3. Department of Chemistry, Purdue University, West Lafayette, IN 47907, USA |
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| Abstract: | Hemilability and nonrigidity in a series of mixed P,P S donor ligands has been studied in the complexes [Pd(P,PS)Cl2], [Pd(η3-C3H5)(P,PS)][SbF6], and [Rh(cod)(P,PS)][SbF6] (P,PS = Ph2P-Q-P(S)Ph2). The effect of bite angle, the rigidity of the ligand backbone, and the role of the ancillary ligands are discussed. |
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