Syntheses and Magnetic Properties Study of Isostructural BiM(2)BP(2)O(10) (M = Co, Ni) Containing a Quasi-1D Linear Chain Structure |
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Authors: | Wei-Long Zhang Zhang-Zhen He Tian-Long Xia Zhong-Zhen Luo Hao Zhang Chen-Sheng Lin Wen-Dan Cheng |
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Institution: | State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences , Fuzhou 350002, People's Republic of China. |
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Abstract: | We present here the structures and magnetism of two quasi-1D linear chain compounds of BiM(2)BP(2)O(10) (M = Co, Ni), which were synthesized by traditional solid-state reactions for the first time. Two title compounds crystallize in the monoclinic system with space group P2(1)/c and feature novel 3D structures with a linear chain structure of {MO(6)}(n) further connected by BP(2)O(10)](7-) anionic groups. The results of magnetic property measurements evidence the antiferromagnetic properties of both compounds in low magnetic field and a field-dependent metamagnetic transition from the antiferromagnetic to ferromagnetic ground state of the BiCo(2)BP(2)O(10) complex. |
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