| 水热合成超分子网络化合物[Mn(phen)_2I_2] (phen=邻菲咯啉)及晶体结构 |
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| 引用本文： | 马天慧,贾林艳,任玉兰,尹永一,董维广,吕孝江.水热合成超分子网络化合物[Mn(phen)_2I_2] (phen=邻菲咯啉)及晶体结构[J].人工晶体学报,2009,38(5):1272-1275. |
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| 作者姓名： | 马天慧 贾林艳 任玉兰 尹永一 董维广 吕孝江 |
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| 作者单位： | 牡丹江师范学院化学系,牡丹江,157012;哈尔滨工业大学化工学院,哈尔滨,150001;牡丹江师范学院化学系,牡丹江,157012 |
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| 基金项目： | 黑龙江省教育厅科学技术研究项目(No.10551320) |
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| 摘 要： | 采用水热法设计并合成了一个新颖的超分子网络化合物Mn(phen)_2I_2],并对其进行了元素分析,红外光谱分析和X-射线单晶衍射分析.结果表明:该化合物属三斜晶系, P_1~-空间群,晶胞参数为:a=0.92705(19) nm,b=1.0370(2) nm,c=1.2775(3) nm,α=77.32(3) °,β=81.26 (3) °,γ=70.30(3) °,V=1.1240(4) nm~3,Z= 2.该化合物通过四种C-H...I氢键相互作用与两种π-π堆积相互作用把各个独立的结构单元连接成了超分子网络化合物.
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| 关 键 词： | 水热合成 配位键 氢键 π-π堆积作用 |
Hydrothermal Synthesis and Crystal Structure of a Supramolecular Network [Mn(phen)2I2] |
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| MA Tian-hui,JIA Lin-yan,REN Yu-lan,YIN Yong-yi,DONG Wei-guang,LV Xiao-jiang.Hydrothermal Synthesis and Crystal Structure of a Supramolecular Network [Mn(phen)2I2][J].Journal of Synthetic Crystals,2009,38(5):1272-1275. |
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| Authors: | MA Tian-hui JIA Lin-yan REN Yu-lan YIN Yong-yi DONG Wei-guang LV Xiao-jiang |
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| Institution: | 1.Department of Chemistry;Mudanjiang Normal College;Mudanjiang 157012;China;2.School of Chemical Engineering and Technology;Harbin Institute of Technology;Harbin 150001;China |
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| Abstract: | A novel supramolecular network Mn(phen)_2I_2] has been rationally designed and synthesized by hydrothermal method and the structure was characterized with elemental analysis, FT-IR spectrum and X-ray diffractometer. It crystallizes in the Triclinic, space group P_1~-, with a= 0.92705(19) nm,b= 1.0370 (2) nm, c=1.2775(3) nm,α=77.32(3) °, β=81.26(3)°,γ=70.30(3) °,V=1.1240(4) nm~3,Z=2. In the title compound Mn(phen)_2I_2], the separated unit cells are constructed into a novel supramolecular network by four types of C-H…I hydrogen-bonded and two kinds of π-π interactions. |
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| Keywords: | hydrothermal synthesis coordinate bond hydrogen bond π-π interactions |
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