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Thermodynamic non-additivity in disordered systems with extended phase space
Authors:Eduard V Vakarin  Jean Pierre Badiali
Institution:(1) Laboratoire de Electrochimie et Chimie Analytique, Ecole Nationale Superieure de Chimie de Paris-Universite Pierre et Marie Curie, 11 rue P. et M. Curie, 75231 Cedex 05 Paris, France
Abstract:Non-additivity effects in coupled dynamic-stochastic systems are investigated. It is shown that there is a mapping of the replica approach to disordered systems with finite replica indexn on Tsallis non-extensive statistics, if the average thermodynamic entropy of the dynamic subsystem differs from the information entropy for the probability distribution in the stochastic subsystem. The entropic indexq is determined by the entropy difference ΔS. In the case of incomplete information, the entropic indexq=1−n is shown to be related to the degree of lost information.
Keywords:disordered systems                      non-extensive entropy                      statistical inference
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