Photochemical reaction of Rh2(CO)4(μ-TPP)(TPP=tetraphenyl-porphyrinato) with pyridine (Py) in benzene. Generation of a mononuclear rhodium(II) porphyrin radical complex Rh(TPP)(Py) |
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| Authors: | Jin-Wan Huang Liang-Nian Ji An-Kong Hsich T. S. Andy Hor |
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| Affiliation: | 1. Department of Chemistry, Zhongshan University, Guangzhou, P.R. China
2. Department of Chemistry, National University of Singapore, Kent Ridge 0511, Singapore
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| Abstract: | Photolytic decarbonylation of Rh2(CO)4(TPP) (TPP=tetraphenylporphyrinato) with pyridine (Py) in benzene gives an unusual monomeric RhII radical complex Rh(TPP)(Py), which has been characterised by thermal and spectroscopic measurements and by vapour pressure osmosis. |
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