| X-射线衍射法研究稀土催化丁二烯异戊二烯共聚物低温下的结晶 |
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| 引用本文： | 魏学军,莫志深,张宏放,杨毓华.X-射线衍射法研究稀土催化丁二烯异戊二烯共聚物低温下的结晶[J].应用化学,1987,0(5):45-48. |
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| 作者姓名： | 魏学军 莫志深 张宏放 杨毓华 |
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| 作者单位： | 中国科学院长春应用化学研究所 |
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| 摘 要： | 本工作用WAXD法对以环烷酸稀土盐为主的催化剂合成的丁二烯和异戊二烯共聚物(Ln-PBI)在低温下的结晶行为进行了研究。Ln-PBI室温下为非晶态,在低温下,异戊二烯含量(重量)>20%时不能生成结晶;含量(重量)<20%时,可观察到结晶的生成。并且结晶度随结晶温度的下降而增加,晶格常数则逐渐减小。Ln-PBI基本上保持了Ln-PB单斜晶系的结晶结构,其晶区由Ln-PB链段所贡献。
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| 收稿时间： | 1986-06-04 |
| 修稿时间： | 1986-10-23 |
ON THE LOW TEMPERATURE X-RAY DIFFRACTION OF COPOLYMER OF BUTADIENE AND ISOPRENE PREPARED WITH RARE-EARTH CATALYST SYSTEM |
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| Wei Xunjun,Mo Zhishen,Zhang Hongfan,Yan Yuhua.ON THE LOW TEMPERATURE X-RAY DIFFRACTION OF COPOLYMER OF BUTADIENE AND ISOPRENE PREPARED WITH RARE-EARTH CATALYST SYSTEM[J].Chinese Journal of Applied Chemistry,1987,0(5):45-48. |
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| Authors: | Wei Xunjun Mo Zhishen Zhang Hongfan Yan Yuhua |
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| Institution: | Changchun Institute of Applied Chemistry, Academia Sinica |
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| Abstract: | Using WAXD method, the crystalline behaviours of poly (butadiene-co-isoprene) (Ln-PBI) at low temperature were studied. When the weight ratio of butadiene/isoprene is <80/20, the Ln-PBI becomes noncrystalline even at very low temoerature(-110℃). However,when weight ratio is >80/20, the crystallinity of Ln PBI increases with decrease of crystallization temoerature, but the lattice parameters changes insignificantly. The crystal of Ln-PBI is considered mainly contributed by Ln-PB sequences and still belongs to monoclinic system. |
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