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White organic light-emitting device with\ both phosphorescent and fluorescent emissive layers
Authors:Zhang Li-Juan  Hua Yu-Lin  Wu Xiao-Ming  Wang Yu and Yin Shou-Geng
Institution:Laboratory of Display Materials and Photoelectric Devices, Ministry of Education;\Key Laboratory of Photoelectric Materials and Devices of Tianjin,\Institute of Material Physics, Tianjin University of Technology, Tianjin 300384, China
Abstract:This paper reports the fabrication of novel white organic light-emitting device(WOLED) by using a high efficiency blue fluorescent dye $N$-(4-((E)-2-(6-((E)-4-(diphenylamino)styryl)naphthalen-2-yl)vinyl)phenyl)-$N$-phenylbenzenamine ($N$-BDAVBi) and a red phosphoresecent dye bis (1-(phenyl) isoquinoline) iridium (III) acetylanetonate (Ir(piq)WOLED, colour stability, $N$-BDAVBi7860F,7280LThis paper reports the fabrication of novel white organic light-emitting device(WOLED) by using a high efficiency blue fluorescent dye $N$-(4-((E)-2-(6-((E)-4-(diphenylamino)styryl)naphthalen-2-yl)vinyl)phenyl)-$N$-phenylbenzenamine ($N$-BDAVBi) and a red phosphoresecent dye bis (1-(phenyl) isoquinoline) iridium (III) acetylanetonate (Ir(piq)WOLED, colour stability, $N$-BDAVBi7860F,7280LThis paper reports the fabrication of novel white organic light-emitting device(WOLED) by using a high efficiency blue fluorescent dye $N$-(4-((E)-2-(6-((E)-4-(diphenylamino)styryl)naphthalen-2-yl)vinyl)phenyl)-$N$-phenylbenzenamine ($N$-BDAVBi) and a red phosphoresecent dye bis (1-(phenyl) isoquinoline) iridium (III) acetylanetonate (Ir(piq)WOLED, colour stability, $N$-BDAVBi7860F,7280LThis paper reports the fabrication of novel white organic light-emitting device(WOLED) by using a high efficiency blue fluorescent dye $N$-(4-((E)-2-(6-((E)-4-(diphenylamino)styryl)naphthalen-2-yl)vinyl)phenyl)-$N$-phenylbenzenamine ($N$-BDAVBi) and a red phosphoresecent dye bis (1-(phenyl) isoquinoline) iridium (III) acetylanetonate (Ir(piq)$_{2}$(acac)). The configuration of the device was ITO/PVK:TPD/CBP: $N$-BDAVBi /CBP/ BALq: Ir(piq)$_{2}$(acac)/BCP/Alq$_{3}$/LiF:AL. By adjusting the proportion of the dopants ($N$-BDAVBi, Ir(piq)$_{2}$(acac)) in the light-emitting layer, white light with Commission Internationale de l'Eclairage (CIE) coordinates of (0.35, 0.35) and a maximum luminance of 25350cd/m$^{2}$ were obtained at an applied voltage of 22V. The WOLED exhibits maximum external quantum and current efficiency of 6.78{\%} and 12cd/A respectively. By placing an undoped spacer CBP layer between the two light-emitting layers and using BCP as hole blocking layer, the colour stabilization slightly changed when the driving voltage increased from 6 to 22\,V.
Keywords:WOLED  colour stability  $N$-BDAVBi
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