Radical addition of 2-trichloromethyl-1,3-dioxolane to vinyltrimethylsilane

Conclusion The addition of 2-trichloromethyl-l,3-dioxolane to vinyltrimethylsilane upon initiation by a system consisting of Fe(CO)₅ and a nucleophilic cocatalyst proceeds to cleavage of a C-Cl bond in the trichloromethyl group with the formation of an adduct containing the dioxolanyl ring.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2351–2353, October, 1986.