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Enantioselective separations by capillary GC on derivatized cyclodextrins. Part 2: Determination of enantiomeric excess of some racemic 2,3-isopropylidene-1,2,3-cyclohexanetriol derivatives on permethyl α-, β-, and γ-cyclodextrins
Authors:K Jaques  W Buda  L Dumortier  J Van der Eycken  Arnold Venema  Pat Sandra
Abstract:Capillary GC on permethyl α-, β-, and γ-cyclodextrins has been applied to separate and quantify the enantiomers of some 2,3-iso-propylidene-1,2,3-cyclohexanetriol derivatives. Quantitative CGC data are compared to those obtained with chiral shift 1H NMR.
Keywords:Capillary gas chromatography (CGC)  Enantioselective separations  (2  3  6-Tri-O-methyl)cyclodextrins  Enantiomeric excess determination  2  3-Isopropylidene-1  2  3-cyclohexanetriol derivatives
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