N-heterocyclic carbene-catalyzed [4 + 1] annulation of phthalaldehyde and imines |
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| Authors: | Sun Fang-gang Ye Song |
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| Affiliation: | Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing, China. |
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| Abstract: | ![]()
The diastereoselective synthesis of cis-2-amino-3-hydroxyindanones was realized by the N-heterocyclic carbene-catalyzed [4 + 1] annulation of phthalaldehyde and imines, which may involve a tandem aza-benzoin reaction and aldol reaction. |
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