Carbaborane‐Substituted 1,2,3‐Triphospholanes and 1‐Aza‐2,5‐diphospholane: New Synthetic Approaches |
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| Authors: | Dr Anika Kreienbrink Sarah Heinicke Thi Thuy Duong?Pham Dr René Frank Dr Peter Lönnecke Prof?Dr Evamarie Hey‐Hawkins |
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| Institution: | Fakult?t für Chemie und Mineralogie, Institut für Anorganische Chemie, Universit?t Leipzig, Johannisallee 29, 04103 Leipzig (Germany), Fax: (+49)?341‐9739319 http://www.uni‐leipzig.de/chemie/hh/ |
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| Abstract: | New phosphorus‐containing, five‐membered P,P,P and P,N,P heterocycles were synthesized and fully characterized. The P,P,P heterocycles, 1,2,3‐triphospholanes, can be synthesized by two different facile pathways, whereas the P,N,P compound, a 1‐aza‐2,5‐diphospholane, can only be obtained with silylamine. |
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| Keywords: | azadiphospholane carbaborane carborane heterocycles phosphorous heterocycles triphospholane |
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