Phosphine‐Catalyzed [3+2] Cycloaddition Reactions of Azomethine Imines with Electron‐Deficient Alkenes: A Facile Access to Dinitrogen‐Fused Heterocycles |
| |
| Authors: | Zhen Li Hao Yu Honglei Liu Lei Zhang Hui Jiang Bo Wang Prof. Dr. Hongchao Guo |
| |
| Affiliation: | Department of Applied Chemistry, China Agricultural University, 2 West Yuanmingyuan Road, Beijing 100193 (P.R. China), Fax: (+86)?10‐6281‐5579 |
| |
| Abstract: | An efficient method for the phosphine‐catalyzed [3+2] cycloaddition reaction of azomethine imines with diphenylsulfonyl alkenes to give dinitrogen‐fused bi‐ or tricyclic heterocyclic compounds in high yields has been described. Moreover, two phenylsulfonyl groups installed on the heterocyclic products could be conveniently removed or transformed to other functional groups, making the reaction more useful. |
| |
| Keywords: | alkenes azomethine imine catalysis cycloaddition reactions phosphine |
|
