Synthesis,characterization, and thermal behavior of palladium(II) complexes containing 4-iodopyrazole |
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| Authors: | Cristiana da Silva Dênis A. M. da Silva Fillipe V. Rocha Carolina V. Barra Regina C. G. Frem Adelino V. G. Netto Antonio E. Mauro Eduardo T. de Almeida |
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| Affiliation: | 1. Departamento de Química Geral e Inorganica, Instituto de Química, UNESP-Univ Estadual Paulista, Araraquara, SP, CEP 14801-970, Brazil
2. Universidade Federal de Alfenas, Alfenas, MG, CEP 31130-000, Brazil
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| Abstract: | The mononuclear pyrazolyl complexes [PdCl2(HIPz)2] (1), [PdBr2(HIPz)2] (2), [PdI2(HIPz)2] (3), [Pd(SCN)2(HIPz)2] (4), and [Pd(NHCOIPz)2] (5) have been prepared. Compound 1 was obtained from the displacement of acetonitrile from [PdCl2(CH3CN)2] precursor by the 4-iodopyrazole (HIPz) ligand, whereas 2–5 were synthesized by substitution of the chlorido in 1 by the respective anionic group. The compounds were characterized by elemental analysis, infrared spectroscopy, and 1H NMR spectroscopy. The thermal behavior of 1–5 has been studied by TG and DTA. The thermal stability of [PdX2(HIPz)2] compounds varies according to the trends X = Cl? < I? ? SCN?< Br?. No stable intermediates were isolated during the thermal decompositions due to the overlap of the degradation processes. The final products of the thermal decompositions were characterized as metallic palladium by X-ray powder diffraction. |
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