A template-directed synthetic approach to halogen-bridged mixed-valence platinum complexes on artificial peptides in solution |
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| Authors: | Tanaka Kentaro Kaneko Kenji Watanabe Yusuke Shionoya Mitsuhiko |
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| Institution: | Department of Chemistry, Graduate School of Science, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo, 113-0033, Japan. |
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| Abstract: | A template-directed synthetic approach to halogen-bridged mixed-valence platinum complexes has been performed in organic media using, for instance, a synthetic peptide bearing two bis(ethylenediamine)-based Pt(IV) complexes with two axial bromide anionic ligands, (Pt(IV)Br2(en))2](RSO3)4, and a Pt(II)(en)2](RSO3)2 complex (R = (C12H25OCH2)2CHO(CH2)3-). |
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