Synthesis and hydrosilation of multi-vinyl branched siloxane for self-healing system |
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Authors: | Xiao Yun Fu Zheng Ping Fang Hai Tang Yang Li Fang Tong |
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Institution: | a Institute of Polymer Composites, Zhejiang University, Hangzhou 310027, China;b Key Laboratory of Macromolecular Synthesis and Functionalization (Zhejiang University),Ministry of Education, Hangzhou 310027, China |
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Abstract: | In this work, the preparation of α, ω-dichloride-terminated multi-vinyl branched siloxane 1 (yield: 57.1%) used for self-healing polymer composites were synthesized via ring-opening of 1,3,5,7-tetravinyl-1,3,5,7-tetramethyl-cyclotetrasiloxane (D4Vi) in the presence of vinylmethydichlorosilane (VM-32). I was hydrogenated by aluminum lithium hydride (LiAlH4) to get self-healing monomer 2 (yield: 79.8%) which contained both Si-H bonds and Si-vinyl bonds. Then hydrosilation occurred between these two bands and finally silicone 3 was obtained, showing the potential of self-healing. |
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Keywords: | Ring-opening Hydrogenation Hydrosilylation Vinylmethydichlorosilane 1 3 5 7-Tetravinyl-1 3 5 7-tetxamethyl-cyelotetrasiloxane |
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