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A stable alkyl hydride of a first row transition metal |
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| Authors: | MacAdams Leonard A Buffone Gerald P Incarvito Christopher D Golen James A Rheingold Arnold L Theopold Klaus H |
| Institution: | Department of Chemistry and Biochemistry, Center for Catalytic Science and Technology, University of Delaware, Newark, DE 19716, USA. |
| Abstract: | Hydrogenolysis of a Cr(III) dialkyl precursor produced a binuclear chromium complex with a bridging hydride and a bridging alkyl; this structurally characterized organometallic compound is thermally very stable and does not undergo the expected reductive elimination of alkane. |
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