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The kinetics of radiation induced hydrogen abstraction by CCl3 radicals in the liquid phase: Cyclanes |
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| Authors: | Zeev B. Alfassi Liviu Feldman |
| Abstract: | The kinetics of gamma-radiation induced free radicals reactions in carbon tetrachloride solutions of cyclohexane, cyclooctane and cyclododecane were studied in the range of 27–190°C. The activation energies found were in the order c? C6H12 > c? C12H24 > c? C8H16, which was explained as due to their ring strain which has the same order. The following log k1 was obtained using the known Arrhenius parameters for CCl3 radical recombination:  |
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