1,3-dipolar addition of pyridine N-imine to acetylenes and the use of C-13 NMR in several structural assignments |
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Authors: | Paul L. Anderson James P. Hasak Alicia D. Kahle Nicholas A. Paolella Michael J. Shapiro |
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Abstract: | Addition of pyridine-N-imine to a variety of acetylenic mono- (Scheme I) and di- (Scheme II) carboxylic ester dipolarophiles was carried out. Several of the 3-azapyrrocoline esters obtained were further converted into acids, amides and hydrazides as shown in Schemes I and II. |
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