Kinetics and Mechanism of Monomolecular Heterolysis of Commercial Organohalogen Compounds: XXX.1 Correlation Analysis of Solvation Effects in Heterolysis of tert-Butyl Chloride |
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| Authors: | Dvorko G F Zaliznyi V V Ponomarev N E |
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| Institution: | (1)  Kievskii politekhnicheskii institut , National Technical University of Ukraine, Kiev, Ukraine |
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| Abstract: | Quantitative analysis of the effect of solvent parameters on the rate of heterolysis of tert-butyl chloride was performed; the reaction rate is fairly described by the polarity, polarizability, and electrophilicity parameters or by the ionizing ability parameter, while the nucleophilicity of the solvent has no rate effect. A negative effect of nucleophilic solvation was revealed in protic solvents. |
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