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MELTING BEHAVIOR OF LOW ETHYLENE CONTENT POLYPROPYLENE COPOLYMERS WITH AND WITHOUT NUCLEATING AGENTS
作者姓名:张瑞云  罗筱烈  王群华  马德柱
作者单位:Department of Materials Science and Engineering,Academia Sinica Structure Research Laboratory,University of Science and Technology of China,Hefei,Anhui 230026,Department of Materials Science and Engineering,Academia Sinica Structure Research Laboratory,University of Science and Technology of China,Hefei,Anhui 230026,Department of Materials Science and Engineering,Academia Sinica Structure Research Laboratory,University of Science and Technology of China,Hefei,Anhui 230026,Department of Materials Science and Engineering,Academia Sinica Structure Research Laboratory,University of Science and Technology of China,Hefei,Anhui 230026
摘    要:The melting behavior of polypropylene (PP) and low ethylene content polypropylenecopolymer with and without nucleating agent samples crystallized under both isothermal and non-isothermal conditions were studied by Differential Scanning Calorimeter (DSC) and X-raydiffraction. Multiple melting behavior were observed depending on the existence of nucleatingagent and crystallization conditions. The observed phenomena have been discussed by the effect ofnucleating agent on perfection of crystal and the melting and recrystallization of imperfect crystalto a more perfect crystal during the heating process of samples.

收稿时间:1993-04-14

MELTING BEHAVIOR OF LOW ETHYLENE CONTENT POLYPROPYLENE COPOLYMERS WITH AND WITHOUT NUCLEATING AGENTS*
ZHANG Ruiyun,LUO Xiaolie,WANG Qunhua,MA Dezhu.MELTING BEHAVIOR OF LOW ETHYLENE CONTENT POLYPROPYLENE COPOLYMERS WITH AND WITHOUT NUCLEATING AGENTS[J].Chinese Journal of Polymer Science,1994,0(3):246-255.
Authors:ZHANG Ruiyun  LUO Xiaolie  WANG Qunhua  MA Dezhu
Institution:Department of Materials Science and Engineering; Academia Sinica Structure Research Laboratory; University of Science and Technology of China; Hefei; Anhui
Abstract:The melting behavior of polypropylene (PP) and low ethylene content polypropylenecopolymer with and without nucleating agent samples crystallized under both isothermal and non-isothermal conditions were studied by Differential Scanning Calorimeter (DSC) and X-raydiffraction. Multiple melting behavior were observed depending on the existence of nucleatingagent and crystallization conditions. The observed phenomena have been discussed by the effect ofnucleating agent on perfection of crystal and the melting and recrystallization of imperfect crystalto a more perfect crystal during the heating process of samples.
Keywords:Melting behavior  Crystal form  DSC  PP copolymer  Nucleating agent
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