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Kinetics and Mechanism of Monomolecular Heterolysis of Commercial Organohalogen Compounds: XXXV.1 Solvation Effects on the Activation Parameters of Heterolysis of 1-Bromo-1-methylcyclopentane and 1-Bromo-1-methylcyclohexane. Correlation Analysis of Solvation Effects
Authors:Dvorko  G F  Koshchii  I V  Ponomareva  E A
Institution:(1) Kievskii politekhnicheskii institut National Technical University of Ukraine, Kiev, Ukraine
Abstract:Kinetics of heterolysis of 1-bromo-1-methylcyclopentane and -cyclohexane in protic and aprotic solvents were studied. Correlation analysis of the effect of solvent parameters on DeltaG ne, DeltaH ne, and DeltaS ne was performed.
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