New synthesis of carbazole-1,4-quinone using a tandem ring-closing metathesis and dehydrogenation reaction under oxygen atmosphere, and its application to the synthesis of murrayaquinone A |
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Authors: | Takashi NishiyamaTominari Choshi Kohdai KitanoSatoshi Hibino |
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Affiliation: | Graduate School of Pharmacy & Pharmaceutical Sciences, and Faculty of Pharmacy & Pharmaceutical Sciences, Fukuyama University, Fukuyama, Hiroshima 729-0292, Japan |
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Abstract: | A tandem ring-closing metathesis and dehydrogenation reaction under oxygen atmosphere was newly developed to the synthesis of carbazole-1,4-quinones. This new tandem reaction was applied to the synthesis of murrayaquinone A in four steps. |
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Keywords: | Carbazole-1,4-quinone Murrayaquinone A Ring-closing metathesis Dehydrogenation Tandem reaction |
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