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New synthesis of carbazole-1,4-quinone using a tandem ring-closing metathesis and dehydrogenation reaction under oxygen atmosphere, and its application to the synthesis of murrayaquinone A
Authors:Takashi NishiyamaTominari Choshi  Kohdai KitanoSatoshi Hibino
Affiliation:Graduate School of Pharmacy & Pharmaceutical Sciences, and Faculty of Pharmacy & Pharmaceutical Sciences, Fukuyama University, Fukuyama, Hiroshima 729-0292, Japan
Abstract:
A tandem ring-closing metathesis and dehydrogenation reaction under oxygen atmosphere was newly developed to the synthesis of carbazole-1,4-quinones. This new tandem reaction was applied to the synthesis of murrayaquinone A in four steps.
Keywords:Carbazole-1,4-quinone   Murrayaquinone A   Ring-closing metathesis   Dehydrogenation   Tandem reaction
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