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Features of the mechanism of oxidative dehydrodimerization of propynol
Authors:Lidiya G Fedenok  Mark S Shvartsberg
Institution:Institute of Chemical Kinetics and Combustion, Siberian Branch of Russian Academy of Sciences, Novosibirsk 630090, Russia
Abstract:Analysis of kinetic regularities for the propynol oxidative coupling under the action of cupric salts in pyridine and in the presence of a buffer is undertaken. The reaction mechanism, including the formation of Cu(I) acetylides, is considered.
Keywords:Oxidative dehydrodimerization  Mechanism  Propynol
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