Synthesis and properties of novel calix[4]arene derivatives bearing fluorogenic coumarin units |
| |
Authors: | He Wen Wang Ya Qing Feng Jin Qiang Xue Chan Xiao |
| |
Institution: | School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China |
| |
Abstract: | Four novel calix4]arene derivatives 5-8 bearing four fluorogenic coumarin units attached via imino group acting also as binding sites at the upper rim have been prepared and characterized by IR, 1H NMR and MS. Compounds 5-8 adopt a cone conformation. Their complexation properties to different heavy and transition metal ions have been studied by UV-vis spectroscopy. Compounds 5, 6, 8 show selective recognition to Fe3 and Cr3 . |
| |
Keywords: | Calixarenes Coumarin Imino Complexation |
本文献已被 CNKI 维普 万方数据 ScienceDirect 等数据库收录! |
| 点击此处可从《中国化学快报》浏览原始摘要信息 |
| 点击此处可从《中国化学快报》下载免费的PDF全文 |