Synthesis and Characterization of Monomeric Aryloxo Palladium Complexes of the Type [Pd(N–N)(OAr)(C6F5)].
Crystal Structure of [Pd(tmeda)(C6F5)(OC6H4NO2‐p)] |
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Authors: | Jos Ruiz M Teresa Martínez Consuelo Vicente Venancio Rodríguez Gregorio Lpez Jos Prez Penny A Chaloner Peter B Hitchcock |
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Institution: | José Ruiz,M. Teresa Martínez,Consuelo Vicente,Venancio Rodríguez,Gregorio López,José Pérez,Penny A. Chaloner,Peter B. Hitchcock |
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Abstract: | Mononuclear palladium‐hydroxo complexes of the type Pd(N–N)(C6F5)(OH)](N–N) = 2,2′‐bipyridine (bipy), 4,4′‐dimethyl‐2,2′‐bipyridine (Me2bipy), 1,10‐phenantroline (phen) or N,N,N′,N′‐tetramethylethylenediamine (tmeda) react with phenols ArOH in tetrahydrofuran giving the corresponding aryloxo complexes Pd(N–N)(C6F5)(OAr)]. Elemental analyses and spectroscopic (IR, 1H and 19F) methods have been used to characterize the new complexes. The X‐ray crystal structure of Pd(tmeda)(C6F5)(OC6H4NO2‐p)] has been determined. In the crystal packing the planes defined by two C6H4 rings show a parallel orientation. There are also intermolecular C–H···F and C‐H···O hydrogen bonds. |
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Keywords: | Palladium Aryloxo Mononuclear complexes Crystal structure |
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