High pressure effect on the chemoselectivity of catalyzed [2+2] and [2+2+2] addition reactions involving acetylenic esters |
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| Authors: | M. Paradopoulos R. Ben Salem G. Jenner |
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| Affiliation: | Laboratorie de Piézochimie Organique, EHICS, Université Louis Pasteur , 67008, Strasbourg, France |
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| Abstract: | ![]()
Abstract The chemoselectivity is changed by pressure in the catalyzed addition of propynoates to norbornadiene, but is not altered in the corresponding addition to norbornene. |
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| Keywords: | chemoselectivity cycloadditions volume of activation |
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