Thermodynamic functions of buthylderivatives of ferrocene |
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| Authors: | O V Krol A I Druzhinina R M Varushchenko P A Zhizhko M D Reshetova N E Borisova N V Chelovskaya |
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| Institution: | 1.Department of Chemistry,Moscow State University,Moscow,Russia |
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| Abstract: | The heat capacity of isobuthanoylferrocene, C5H5FeC5H4-COCH(CH3)2, was measured by low-temperature adiabatic calorimetry. The purity, temperature, and enthalpy of fusion were obtained. The
ideal gas thermodynamic functions were derived at T = 298.15 K. The purity and thermodynamic functions of fusion of isobuthylferrocene, C5H5FeC5H4-CH2CH(CH3)2, were obtained by differential scanning calorimetry. The sample was synthesized by the reduction of isobuthanoylferrocene
obtained by the direct acylation of ferrocene. |
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