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Metal-free aerobic oxidative coupling of amines to imines
Authors:Liu Lianghui  Zhang Siyu  Fu Xuefeng  Yan Chun-Hua
Affiliation:Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering, Peking University, Beijing, 100871, China.
Abstract:Oxidative coupling of primary amines to imines is achieved with high to moderate yields by refluxing suspensions of amines and water under one atmosphere dioxygen without any additives. Tandem acid-free aza Diels-Alder reactions for synthesis of N-alkyl-4-pyridones are also accomplished.
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